SINTESIS SILIKA MESOPORI TERSULFONASI DARI ABU DAUN BAMBU PETUNG (Dendrocalamus asper)

  • Sari Clara Precelia Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Mulawarman
  • RR Dirgarini Julia Nurlianti Subagyono Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Mulawarman
  • Chairul Saleh

Abstract

Research on the synthesis of sulfonated mesoporous Silica from bamboo leaves ash (Dendrocalamus asper) as Heterogeneous Acid Catalyst has been conducted. Bamboo Leaf Ashfish serves as a source of silica for the manufacture of Mesoporous Silica. The research phase consisted of synthesis of MSU-H with surfactant template method, mesoporous silica modification with 3-mercaptopropyl-trimethoxysilane (MPTMS) using post grafting method. The mesoporous silica has a pore volume of 1.03 cm3/g, a surface area of 150 m2/g and a pore diameter of 27.5 nm. The FT-IR spectrum of mesoporous silica before sulfonation shows the presence of Si-O-Si, and Si-OH functional groups while that of Mesoporous silica after sulfonation shows the presence of Si-O-Si, Si-O, Si-OH and –SO3H functional groups.

Keyword
Daun Bambu Petung, Katalis, Silika Mesopori, FT-IR, Surfactant template, post grafting

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References

[1] Priyanto, A., Ilmu, F., Dan, T., Islam, U., A.Walisongo, N. 2015. Sintesis dan aplikasi silika dari abu daun bambu petung (Dendrocalamus asper (Schult. f.) Backer ex Heyne) untuk mengurangi kadar ammonium dan nitrat pada limbah cair tahu. Skripsi. Semarang: Universitas Islam Negeri Walisongo.
[2] Pirez, C., A. F. Lee., C. Manayil., C. M. Parlett., C. K. Wilson. 2012. Hydrothermal saline promoted grafting : a new route to sulfonic acid SBA-15 silica with ultra-high acid site loading for biodiesel synthesis. Green Chemistry : 16 : 4506-4509.
[3] Alfaruqi, M. H. 2008. Pengaruh konsentrasi hidrogen klorida (HCl) dan temperatur perlakuan hidrotermal terhadap kristalinitas material mesopori silika SBA-15, 5– 18.
[4] Nasikin, M dan Susanto, B. H. 2010 Katalis Heterogen, Edisi Pertama, Penerbit Universitas Indonesia.
[5] Chakravert, A., Mishra, P., and Banerjee, H. 1998 “Investigation of raw and acid-leached rise husk for pare amorphous white silica”. Journal of Material Sciene, 23(1). 21-24.
[6] A. Maleki, M. Hamidi. 2017 Mesoporous Silica Materials: From Physio-Chemical Properties to Enhanced Dissolution of Poorly Water-Soluble Drugs. Journal of Controlled Release Journal of Material Sciene, University Italy Expert Opin. Drug Deliv. 13 (2016) 171–81.
[7] Adamson AW. 1990, Physical Chemistry of Surfaces, John Wiley & Sons, Inc, New York.
[8] Gregg SJ &Sing KSW. 1982. Adsorption, Surface Area and Porosity. 2nd Edition, London: Academic Press.
[9] Dai, W., Zhou, Y., Li, S., Li, W., Su, W., Sun, Y., Zhou, L. 2006. Thiophene capture with complex adsorbent SBA-15/Cu(I). Ind. Eng. Chem. Res. 45, 7892–7896.
[10] Bae, J.A. Hwang Hee Hwang, Ki-Chang Song. 2010. Synthesis of Functionalized Mesoporous Material with Various Organo-Silanes.
[11] Taffarel, S. D. Rubio. Adsorption of sodium dodecyl benzene for zeolite, 4th ed. New York. Elsevier Science Publisher. B.V.
[12] Lois, P. E. 2015. Sintesis surfaktan metil ester sulfonat dari metil ester minyak biji ketapang (Terminalia catappa Linn.) melalui reaksi sulfonasi pada berbagai jumlah metanol. Skripsi. Fakultas Matematika dan Ilmu Pengetahuan Alam: Universitas Mulawarman.
[13] Silverstein, R. M., Bassler, G. C., Morrill, T. C. 2001. Spectrometric identification of organic compounds, 5th ed. New York. John willey & sons.
[14] Cheng, Y.W. 2005. Preparation and characterization of nanosized ZSM-5 Zeolite in the absence of organik template. Materials Latters. Volume 59: 3427-3430.
Published
2018-03-28
How to Cite
PRECELIA, Sari Clara; SUBAGYONO, RR Dirgarini Julia Nurlianti; SALEH, Chairul. SINTESIS SILIKA MESOPORI TERSULFONASI DARI ABU DAUN BAMBU PETUNG (Dendrocalamus asper). JURNAL ATOMIK, [S.l.], v. 3, n. 1, p. 61-67, mar. 2018. ISSN 2549-0052. Available at: <http://jurnal.kimia.fmipa.unmul.ac.id/index.php/JA/article/view/525>. Date accessed: 19 dec. 2018.
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