SYNTHESIS OF CELLULOSE ACETATE FROM OIL PALM EMPTY FRUIT BUNCH AND ITS PROPERTIES AS POLYMER ELECTROLYTE MEMBRANES ON LITHIUM ION BATTERY

  • Nurhadini Nurhadini Program Studi Kimia Universitas Bangka Belitung
  • I Made Arcana Jurusan Kimia, Institut Teknologi Bandung

Abstract

Biodegradable polymer electrolyte utilization on lithium ion battery is increasingly considered to prevent any waste. This study was conducted to synthesis cellulose acetate from oil palm empty fruit bunch and its properties as polymer electrolyte membranes on lithium ion battery. This study was done by extracting cellulose from oil palm empty fruit bunch. That cellulose was acetylated become cellulose acetate and characterized its functional group. Further, polymer electrolyte was synthesized with composition 25/60/15(%b/b) (SAS/PEO/LiClO4). The properties of polymer electrolyte membranes were characterized by analysis thermal properties, ionic conductivity and mechanical properties. Based on functional group data, synthetic cellulose acetate had similar the main functional group with commercial cellulose acetate. Synthetic cellulose acetate contained 27% acetyl with 1,4 substitution degree. Analysis thermal properties showed that the decomposition of SAS/PEO/LiClO4 polymer electrolyte membranes was started above 260oC.  The ionic conductivity 10,81 x 10-4 S/cm of  these polymer electrolyte membranes was 10,81 x 10-4 S/cm. Analysis of mechanic properties were 0,05 MPa stress, 14,23 MPa elongation and 0,35 MPa Modulus Young. SAS/PEO/LiClO4 polymer electrolyte membranes had higher ionic conductivity than SAK/PEO/LiClO4 polymer electrolyte membranes. However, SAS/PEO/LiClO4 polymer electrolyte membranes had lower thermal and mechanic properties than SAK/PEO/LiClO4 polymer electrolyte membranes.


 

Keyword
oil palm empty fruit bunch, polymer electrolyte membranes, lithium ion battery

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References

[1] Direktorat Jendral Perkebunan. (2016). Statistik Perkebunan Indonesia Komoditas Kelapa Sawit 2014 – 2016.
[2] Kamal, N. (2012). Karakterisasi Dan Potensi Pemanfaatan Limbah Sawit. Teknik Kimia, ITENAS. Bandung
[3] Warsito, J., Sabang, S.M., Mustapa. (2016). Pembuatan Pupuk Organik Dari Limbah Tandan Kosong Kelapa Sawit, J. Akad. Kim. 5(1), 8-15
[4] Saputra, E., Bahri, S., Hs, E. (2007). Bio-Oil dari Limbah Padat Sawit. Jurnal Rekayasa Kimia dan Lingkungan, 6(2), 45-49
[5] Sunaryo, A., Anggito, M., and Sumringahgesit, M. (2013). Hydrolysis of a lignocellulosic materials oil palm empty fruit bunch for ethanol production, Biomaterial Technology ,803, 1–11
[6] Gurning, N. (2013). Pembuatan Beton Serat Tandan Kosong Kelapa Sawit, TELAAH Jurnal Ilmu Pengetahuan dan Teknologi, 31 (1), 13-20
[7] Bahmid, N.A.(2014). Pengembangan Nanofiber Selulosa Asetat Dari Selulosa Asetat Tandan Kosong Kelapa Sawit Untuk Pembuatan Bioplastik, Sekolah Pascasarjana institute Pertanian Bogor, Tesis.
[8] Fonseca, C.P., Rosa, D.D., Gaboardi,F., Neves, S.(2006). Development of a biodegradable polymer electrolyte for rechargeable batteries. Short communication, Journal of Power Sources, 155, 381–384
[9] Gurusiddappaa, J., Madhurib, W.,Suvarnaa, P.R., Dasan,K.P. (2016). Studies on the morphology and conductivity of PEO/LiClO4. Materials Today: Proceedings, 3, 1451–1459
[10] Laksono, E.W., Marfuatun, Aji, D.(2016). Conductivity of Cellulose Acetate Membranes from Pandan Duri Leaves (Pandanus tectorius) for Li-ion Battery. MATEC Web of Conferences, 6, doi: 10.1051/ /20166404001
[11]Selvakumar, M. Bhat, D.K. (2008). LiClO4 Doped Cellulose Acetate as Biodegradable Polymer Electrolyte for Supercapacitors. Journal of Applied Polymer Science . doi 10.1002/app
[12] Nurhadini dan Arcana, I,M. (2015).Synthesis of polymer electrolyte from cellulose acetate/poly(ethylene oxide)/LiClO4 for Ion Battery Application, The 5th International Conference On Mathematic And Natural Sciences, AIP.Conf.Proc.1677,070003-4, doi: 10.1063/1.4930707
[13] Filho, G.R., Monteiro, D.S., Meireles, C.S., Assunção, R.M.N., Cerquira, D.A., Barud, H.S., Ribero, S.J.L., Messadeq, Y. (2008). Synthesis and characterization of cellulose acetate produced from recycled newspaper, Elsevier, Carbohydrate Polymers, 73, 74–82
[14] Samios, E., Dart, R.K., Darwis, J.V. (1997). Preparation, Characterization and biodegradation studies of cellulose acetate, Polymer, 12, 3045-3054.
[15] Bhattacharya, D., Germinario, L.T. dan Winter, W.T. (2008). Isolation, preparation and characterization of cellulose microfibers obtained from bagasse. Carbohydrate Polymers, 73, 371–377
[16] Hamisan, A.F., Abd-Aziz,S., Kamarudin,K., Shah, U.K.M., Shahab, N., Hassan, M.A. (2008). Delignification of Oil Palm Empty Fruit Bunch Using Chemical and Microbial Pretreatment Methods. Academic Journal Inc., International Journal of Agricultural Research, ISSN 1816-4897
[17] Barud, S.H, Adalberto, M.. Santos, D.B., Assunc, R.M.N., Meireles, C.S., Cerqueira, D.A., Filho, R.G., Ribeiro, C.A., Messaddeq, Y., Ribero, S.J.L. (2008). Thermal behavior of cellulose acetate produced from homogeneous acetylation of bacterial cellulose. Thermochimica Acta, 471, 61-69.
Published
2018-05-30
How to Cite
NURHADINI, Nurhadini; ARCANA, I Made. SYNTHESIS OF CELLULOSE ACETATE FROM OIL PALM EMPTY FRUIT BUNCH AND ITS PROPERTIES AS POLYMER ELECTROLYTE MEMBRANES ON LITHIUM ION BATTERY. JURNAL KIMIA MULAWARMAN, [S.l.], v. 15, n. 2, p. 111-117, may 2018. ISSN 2476-9258. Available at: <http://jurnal.kimia.fmipa.unmul.ac.id/index.php/JKM/article/view/612>. Date accessed: 19 dec. 2018. doi: https://doi.org/10.30872/jkm.v15i2.612.
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Artikel