PEMBUATAN DAN KARAKTERISASI MEMBRAN SELEKTIF ION TIMBAL (II) DENGAN MENGGUNAKAN ETILEN DIAMIN TETRA ASETAT (EDTA) SEBAGAI IONOFOR

  • Ummul Waqifah Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman
  • Aman S. Panggabean
  • Erwin Akkas

Abstract

A research about preparation and characterization of Plumbum (II) ion selective membrane using a PVC based on ethylene diamine tetraacetate as ionophores have been done. Ethylene diamine tetra acetate (EDTA) was able to coordinate with Pb2+ and increase the conductivity of the membrane. Ethylene diamine tetra acetate (EDTA) as the main ingredient mixed with polyvinylchloride (PVC) as a matrix whose first dissolved using tetrahydrofuran (THF), added dioctyl phat alate (DOP) as a plasticizer. The membrane was soaked with Pb2+ for 2 days and membrane absorption ability of EDTA to the metal dopant Pb2+, and measured using atomic absorption spectrophotometer (AAS). Membrane absorption ability of the dopant metal Pb2+ retrieved the percent absorption was 76.01 % at the optimum composition of the membrane with a ratio of EDTA: PVC: DOP is 60: 30: 10. EDTA membrane characterization results with Fourier transform infrared spectroscopy  (FT-IR) showed specific functional groups on the membrane EDTA.

References

[1] Edmonds, T. E. 1988. Chemical Sensor. New York: Blackie and Sons.
[2] Underwood, A. L. dan Day, Ir, R. A. 1986. Analisis Kimia Kuantitatif. Edisi Keenam. Jakarta: Erlangga.
[3] Rivai, H. 1995. Asas Pemeriksaan Kimia. Jakarta: UI Press.
[4] Kolodynska, D., Hubicki, Z. dan Pasieczna, S. 2009. FTIR / PAS Studies of Cu (II)-EDTA Complexes Sorption On The Ion Exchangers. Acta Physica A. Vol 116. pp 340-343
Published
2017-03-01
How to Cite
WAQIFAH, Ummul; PANGGABEAN, Aman S.; AKKAS, Erwin. PEMBUATAN DAN KARAKTERISASI MEMBRAN SELEKTIF ION TIMBAL (II) DENGAN MENGGUNAKAN ETILEN DIAMIN TETRA ASETAT (EDTA) SEBAGAI IONOFOR. JURNAL ATOMIK, [S.l.], v. 2, n. 1, p. 169-174, mar. 2017. ISSN 2549-0052. Available at: <http://jurnal.kimia.fmipa.unmul.ac.id/index.php/JA/article/view/391>. Date accessed: 24 sep. 2017.
Section
Artikel

Keywords

PVC Membrane, Plumbum (II), Ethylene diamine tetra acetate (EDTA)