ANALISIS TOTAL SULFUR TERHADAP SAMPEL FEED GAS DENGAN MEMBANDINGKAN STANDAR GAS DAN STANDAR LIQUID MENGGUNAKAN METODE TS-100V
Abstract
The total sulfur analysis in the feed gas sample by using standard gas and liquid has been researched. The concentration of total sulfur obtained from a calibration curve by using standard gas or liquid by TS - 100V. Based on the analysis of measurement linearity, by making curve a linearity from a standard gas H 2 S was 0.999 and standard liquid dibutyl sulfide was 0.998, where both the standard curve can be as a calibration curve because each the value of the correlation coefficient (r) having worth >0.995. Based on the analysis of measurement precision namely repeatability by measuring a feed gas sample train G as many as 5 times been gained. RSD value was 4.17 in standard gas and 4.70 in standard liquid. Both the calibration curve has been accepted because the relative standard deviation values less than 0.67 from Horwitz and still into get allowed range values from 7.3 to 11%. Based on the analysis of accuracy’s measurement is percent recovery for the standard gas was 100.578% and for standard liquid was 104.380%. Both of them has been accepted because it still fit in the allowed range values 80-110%.
Keywords : Total Sulfur, H 2 S Standard Gas, Standard Liquid Dibutyl Sulphites and TS-100V
Downloads
References
Analytikjena AG. Analytical Solution. 2000. Total Sulphur Determination for Gases, LPG and Related Materials.Multi EA 3000 S.
Anggraeni, R. 2013. Kalibrasi Alat Total Sulfur (TS-100V) Dengan Standar Liquid Dibutilsulfid. Laporan Praktik Kerja Lapangan. Universitas Mulawarman.Samarinda.
AOAC International. 1993. Manual For Peer-Verified Methods Programs. Gaithersburg, MD 20877-2450. USA
Arya W, W. 2001. Dampak Pencemaran Lingkungan. Andi Offset. Yogyakarta
ASTM. 2000. Determination of Total Sulfur in Light Hydrocarbons, Motor Fuels and Oils by Ultraviolet Fluerescence. http://constructionenglish.net/id/astm/.West Conshohocken, PA 19428-2959. United States.
Basset, J., Denney, R.C., Jeffery, G.H., Mendham, J. 1991. Vogel Kimia Analisis Kuantitatif Anorganik. Penerbit Buku Kedokteran EGC. Jakarta.
Chan, C., Lam, C., Herman, Lee, Y.C. and Zhang, X.M. 2004. Analytical Method Validation and Instrument Performance Verification. Canada: John Wiley & Sons.
Chemical, Mitsubishi. 2002. Manual Book Trace Sulfur Analyzer Model TS-100. Mitsubishi Chemical Corporation: Jepang.
Corporation, Thermo Electron. 2005. Total Sulfur in Hydrocarbons Determination According to ASTM D5453 Using The TS 3000. Application Note 420042. The Netherlands is ISO certified.
Corporation, Thermo Electron. 2004. Total Sulfur in Liquefied Petroleum Gas (LPG) Samples by Pulsed-UV-Fluorescence. Application Note AN42012 E 02/04. The Netherlands is ISO certified.
Cotton, F.A., Wilkinson, G. 2007. Kimia Anorganik Dasar. UI Press. Jakarta.Eko. 2011. Pengertian Belerang atau Sulfur. Adenbagoes@Shvoong.com. Diunduh tanggal 22 Agustus 2013 pukul 19.13 WITA.
Ermer, J.H. and Miller, McB. 2005. Method Validation in Pharmaceutical Analysis.A Guide to Best Practice.Weinheim: WILEY-VCH Verlag GmbH & Co. KGaA.
Harmita. 2004. Petunjuk Pelaksanaan Validasi Metode dan Cara Penggunaanya. Majalah Ilmu Kefarmasian Volume. 1 No.3 Desember 2004, Hal 117-135.
Haydt, D. 2001. Determination of Hydrogen Sulfide and Total Sulfur in Natural Gas. Galvanic Applied Sciences.Houston TX 77064.
ISO 13528. 2005. Statistical Methods For Use in Proficiency Testing by Interlaboratory Comparison. Switzerland.
ISO/IEC 17025. 2005(E). General Requirements For The Competence of Testing and Calibration Laboratories.Switzerland.
Kantasubrata, J. 2005. Validasi Metode. Pusat Penelitian Kimia LIPI. Pelatihan Laboratorium Terpadu FMIPA UII.Yogyakarta.
Nasution, M.Q. 2008. Penentuan Kadar Metana Pada Aliran Gas Ke Dietanol Amin,Karbonat, Plant, Dan Train Menggunakan Kromatografi Gas. Laporan Karya Ilmiah. Universitas Sumatera Utara. Medan
Nugroho, A., Wahyono, H. Dan Fatimah, S. 2006. “Validasi Metode Alat ICP-AES Plasma 40 untuk Pengukuran Unsur CR, P, Ti”. Jurnal Pusat Teknologi Bahan Bakar Nuklir, BATAN.12, (2), 100-107.
Prakasita, N. 2012. Cahaya Luminesensi. http://nira15.blogspot.com/2012/09/ cahaya-luminesensi.html. Diunduh tanggal 5 Februari 2014 pukul 13.00 WITA
Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
This license requires that reusers give credit to the creator. It allows reusers to distribute, remix, adapt, and build upon the material in any medium or format, even for commercial purposes. If others remix, adapt, or build upon the material, they must license the modified material under identical terms.
BY: Credit must be given to you, the creator.
SA: Adaptations must be shared under the same terms.
