Sintesis Silika Mesopori Sba-15 Dari Abu Daun Jagung (Zea Mays L)

  • Nasri Nasri Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman
  • R R Dirgarini J. N Subagyono Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman
  • Rahmat Gunawan

Abstract

The synthesis and characterization of  mesoporous silica Santa Barbara Acid-15 (SBA-15) from the ash of corn have been done.  SBA-15 was synthesised using the surfactant template method. SBA-15 from corn leaves  ash has a surface area of 592 m2 / gram, pore volume of 0.99 cm3 / gram and pore diameter of 3.95 nm with pore size ranging from 4.9 nm - 7.1 nm. The SAXS pattern of the bio-SBA-15 showed three typical peaks of SBA-15 with miller indices [100], [110] and [200]. In the FTIR spectrum of  SBA-15, peaks from Si-O-Si, Si-OH and H-O-H from water were observed.


 

Keyword
Corn leaves as, Mesoporous Silica, SBA-15

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References

[1] Sudjana, A., Rifin, A., dan Sudjadi, M.1991. Jagung. Buletin Teknik No.3 Balitbang Pertanian. Balai Penelitian Tanaman Pangan, 41.
[2] Fedeyko, J. M., Vlachos, D. G., dan Lobo, R. F. 2006. Understanding the differences between microporous and mesoporous synthesis through the phase behavior of silica.Microporous and Mesoporous Materials, 90(1–3 SPEC. ISS.), 102–111.
[3] Cui, H., Zhang, Y., Qiu, Z., Zhao, L., danZhu, Y. 2010. Applied Catalysis B : Environmental Synthesis and characterization of cobalt-substituted SBA-15 and its high activity in epoxidation of styrene with molecular oxygen. “Applied Catalysis B, Environmental,”101(1–2), 45–53.
[4] Balgis, R., S. Affandi., H. Setyawan., S. Winardi., A. Purwanto. 2009. A Facile Method for the Production of High Purity Silica Xerogels from Bagasse Ash. Journal. Adv. Powder Tech. 20 : 468-472.
[5] Zhao, D., Huo, Q., Feng, J., Chemelka, B. F., dan Stucky, G. D. 1998. Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses or Highly Ordered, Hydrothermally Stable, Mesoporous Silica Structure, 120, 6024–6036.
[6] Putra, Angke Rienhar. 2017. sintesis Silika Mesopori SBA-15 Abu Daun Bambu Petung (Dendrocalamus Asper (Schult Backer Ex Heyne) dan Pemanfaatannya sebagai Adsorben Metilen Biru. Samarinda: FMIPA Unmul.
[7] Vogel.1985. Analisis Anorganik Kualitatif Makro dan Semi Mikro. Jakarta : PT. Kalman Media Pustaka.
[8] Margolese, D., J. A. Melero, S. C. Christiansen, B. F. Chmelka, & G. D. Stucky. 2000. Direct Syntheses of Ordered SBA-15 Mesoporous Silica Containing Sulfonic Acid Groups. Chemistry of Materials 12: 2448-2459.
[9] Ding, T. P., X. Zhou, J., F. Wan, D., Y. Chen, Z., Y. Wang, C., & Zhang, F.2008. Silicon isotope fractionation in bamboo and its significance to the biogeochemical cycle of silicon, Geochimica et Cosmochimica Acta, No. 72.
[10] Subagyono, Dirgarini J. N, Zhijian Liang, Gregory P. Knowles & Alan L. Chaffe. 2011. Amine Modified Mesocellular Siliceous Foam (MCF) as a Sorbent for CO2.Chemical Engineering Research and and Design. CRC for Greenhouse Gas Technologies, School of Chemistry, Monash University, Clayton Campus, Wellington Road, Victoria 3800.
[11] Rahman, Nurul Barakah A.B, Hamizah Md. Rasid, Hashazirah Mohammad Hassan, and Mohammad Noor Jalil. 2016. Synthesis and Characterization of Mesoporous Silica.Published by The Malaysian Analytical Sciences Society.
[12] Ulfa, M., Trisunaryanti, W., Falah, and Kartini. 2014. Studies of kinetic on thermal decomposition of mesoporous carbon of gelatin by thermogravimetric technique. Int. J.Innov. Appl. Stud., 7, 849–856.
Published
2017-11-29
How to Cite
NASRI, Nasri; SUBAGYONO, R R Dirgarini J. N; GUNAWAN, Rahmat. Sintesis Silika Mesopori Sba-15 Dari Abu Daun Jagung (Zea Mays L). JURNAL KIMIA MULAWARMAN, [S.l.], v. 15, n. 1, p. 60-65, nov. 2017. ISSN 2476-9258. Available at: <http://jurnal.kimia.fmipa.unmul.ac.id/index.php/JKM/article/view/524>. Date accessed: 19 june 2018. doi: https://doi.org/10.30872/jkm.v15i1.524.
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